Name: Your Name (What ever you want)
Email: Your email address is your username
Password: Your live.de account password
Description: live.de
Click Next Button
Hostname: imap-mail.outlook.com
Username: Your email address is your username
Password: Your live.de account password
Hostname: smtp-mail.outlook.com
Username: Your email address is your username
Password: Your live.de account password
Click Save Button
Use SSL: Yes
Authentication: Password
Server Port: 993
Use SSL: Yes
Authentication: Password
Server Port: 587
You can login live.de and Signup for live.de new account on your iPhone from here.